[3-(2,3-Epoxypropoxy)-propyl]-trimethoxysilane for synthesis
Silane coupler KH-560
CAS: 2530-83-8
Molecular Formula: C9H20O5Si
[3-(2,3-Epoxypropoxy)-propyl]-trimethoxysilane for synthesis - Names and Identifiers
| Name | Silane coupler KH-560 |
| Synonyms | GLYMO GOPTS Silane coupler KH-560 Silane coupling agent KH-560 3-Glycidoxypropyltrimethoxysilane γ-glycidoxypropyltrimethoxysilane (GLYCIDOXYPROPYL)TRIMETHOXYSILANE 3-Glycidoxypropyltrimethoxy silane 3-Glycidyloxypropyltrimethoxysilane (3-Glycidoxypropyl)trimethoxysilane (3-Glycidyloxypropyl)-trimethoxysilane 2,3-Epoxypropoxy propyltrimethoxysilicane γ-(2,3-epoxypropoxy)propytrimethosysilane [3-(2,3-Epoxypropoxy)-propyl]-trimethoxysilane for synthesis DOW CORNING Z-6040 EPOXYFUNCTIONAL SILICONE ADHESIVE ADDITIVE |
| CAS | 2530-83-8 |
| EINECS | 219-784-2 |
| InChI | InChI=1/C9H20O5Si/c1-10-15(11-2,12-3)6-4-5-13-7-9-8-14-9/h9H,4-8H2,1-3H3/t9-/m0/s1 |
| InChIKey | BPSIOYPQMFLKFR-UHFFFAOYSA-N |
[3-(2,3-Epoxypropoxy)-propyl]-trimethoxysilane for synthesis - Physico-chemical Properties
| Molecular Formula | C9H20O5Si |
| Molar Mass | 236.34 |
| Density | 1.070g/mLat 20°C |
| Melting Point | -50°C |
| Boling Point | 120°C2mm Hg(lit.) |
| Flash Point | >230°F |
| Water Solubility | Miscible with alcohols, ketones and aliphatic or aromatic hydrocarbons. Immiscible with water. |
| Solubility | Soluble in water, soluble in acetone, benzene and ether. |
| Vapor Presure | 0-12790Pa at 20-25℃ |
| Appearance | Clear Liquid |
| Specific Gravity | 1.07 |
| Color | Clear |
| BRN | 4308125 |
| Storage Condition | Store below +30°C. |
| Stability | Moisture Sensitive |
| Sensitive | Moisture Sensitive |
| Refractive Index | n20/D 1.429(lit.) |
| MDL | MFCD00005144 |
| Physical and Chemical Properties | Colorless transparent liquid. The product is soluble in a variety of organic solvents, easy hydrolysis, condensation to form polysiloxane, overheating, light, peroxide in the presence of easy polymerization. |
| Use | Can make two kinds of material coupling, improve the mechanical strength of products, improve the electrical properties of composite materials, weather resistance and corrosion resistance, suitable for glass fiber reinforced plastic/adhesive |
[3-(2,3-Epoxypropoxy)-propyl]-trimethoxysilane for synthesis - Risk and Safety
| Risk Codes | R36/38 - Irritating to eyes and skin. R21 - Harmful in contact with skin R52 - Harmful to aquatic organisms R41 - Risk of serious damage to eyes |
| Safety Description | S28A - S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S24/25 - Avoid contact with skin and eyes. |
| WGK Germany | 2 |
| RTECS | VV4025000 |
| FLUKA BRAND F CODES | 10-21 |
| TSCA | Yes |
| HS Code | 29310095 |
| Packing Group | III |
| Toxicity | LD50 oral in rat: 22600uL/kg |
[3-(2,3-Epoxypropoxy)-propyl]-trimethoxysilane for synthesis - Upstream Downstream Industry
| Raw Materials | Fumes, silica Methyl alcohol |
[3-(2,3-Epoxypropoxy)-propyl]-trimethoxysilane for synthesis - Reference
| Reference Show more | 1. Chen Yunbo, Liu Huan, Zhang Zhaoling, et al. Preparation of Amino-Containing Silica Sol and Its Flame Retardant Finishing for Silk Fabrics [J]. Silk 2018 55(003):1-6. 2. Zheng, Longhui, et al. "High-k 3D-barium titanate foam/phenolphthalein poly (ether sulfone)/cyanate ester composites with frequency-stable dielectric properties and extremely low dielectric loss under reduced concentration of ceramics." Applied Surface Sci 3. Liu, Shenglin, et al. "Graphene oxide modified by zirconium dioxide to enhance the corrosion resistance of Zinc/Aluminum coatings." Diamond and Related Materials 108 (2020): 107868.https://doi.org/10.1016/j.diamond. 2020.107868 4. Zhang, Chen, et al. "Fabrication of surface charge pH-sensitive multi-bumpy small magnetic bead with ultrahigh magnetic content and its ultrahigh loading capacity and salt-free rapid isolation for DNA." Journal of Pharmaceutical and Biomedical Analysis 189 5. Fang, Hao, et al. "Aramid fibre-based wearable electrochemical capacitors with high energy density and mechanical properties through chemical synergistic combination of multi-coatings." Electrochimica Acta 284 (2018): 149-158.https://doi.org/10.1016/j.elec 6. [IF=6.901] Hao Fang et al."Aramid fibre-based wearable electrochemical capacitors with high energy density and mechanical properties through chemical synergistic combination of multi-coatings."Electrochim Acta. 2018 Sep;284:149 7. [IF=3.125] Wentao Hao et al."Polyurethane electrospun mats strengthened and toughened by physically blended polyhedral oligomeric silsesquioxane."J Appl Polym Sci. 2014 Oct;131(20): 8. [IF=18.808] Xiaojuan Qian et al."Polysiloxane Cross-Linked Mechanically Stable MXene-Based Lithium Host for Ultrastable Lithium Metal Anodes with Ultrahigh Current Densities and Capacities."Adv Funct Mater. 2021 Feb;31(6):2008044 9. [IF=6.707] Wenyan Zhao et al."Environmentally-friendly superhydrophobic surface based on Al2O3@KH560@SiO2 electrokinetic nanoparticle for long-term anti-corrosion in sea water."Appl Surf Sci. 2019 Aug;484:307 10. [IF=5.645] Bin Liang et al."Bio-based organic-inorganic hybrid UV-curable hydrophobic coating prepared from epoxidized vegetable oils."Ind Crop Prod. 2021 May;163:113331 11. [IF=3.935] Chen Zhang et al."Fabrication of surface charge pH-sensitive multi-bumpy small magnetic bead with ultrahigh magnetic content and its ultrahigh loading capacity and salt-free rapid isolation for DNA."J Pharmaceut Biomed. 2020 Sep;189:113439 12. [IF=2.153] Qin Siyuan et al."Study on Flame Retardancy and Interface Performance of Carbon Fiber Reinforced Epoxy Composites Based on a Modified N-P-Si-containing Sizing Agent."Fiber Polym. 2021 Jun;22(6):1664-1674 13. [IF=8.528] Yang Lyu et al.3D printing nanocomposites with controllable “strength-toughness” transition: Modification of SiO2 and construction of Stereocomplex Crystallites.Compos Sci Technol. 2022 Feb;218:109167 14. [IF=10.998] Lifu Lin et al."Additive manufacturing of complex-shaped and high-performance aluminum nitride-based components for thermal management."Addit Manuf. 2022 Apr;52:102671 15. [IF=3.125] Yao Zhang et al."High-performance fiber-reinforced composites with a polydopamine/epoxy silane hydrolysis-condensate bilayer on surface of ultra-high molecular weight polyethylene fiber."Journal Of Applied Polymer Science. 2021 Dec 27 16. [IF=4.759] Yang Zhao et al."Pseudomorphic synthesis of bimodal porous silica microspheres for size-exclusion chromatography of small molecules."J Chromatogr A. 2022 Feb;1664:462757 17. [IF=7.312] Qinyu Wang et al."Compressible amino-modified carboxymethyl chitosan aerogel for efficient Cu(II) adsorption from wastewater."SEPARATION AND PURIFICATION TECHNOLOGY. 2022 Jul;293:121146 |
[3-(2,3-Epoxypropoxy)-propyl]-trimethoxysilane for synthesis - Reference Information
| LogP | -2.6-0.5 at 20℃ |
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| silane coupling agent KH-560 | silane coupling agent KH-560 is the earliest widely used coupling agent and has a history of more than 40 years. One end of its structure has active groups that can react with epoxy, phenolic, polyester and other synthetic resin molecules, such as amino, vinyl, etc. The other end is the alkoxy group (such as methoxy, ethoxy, etc.) or chlorine atoms connected to silicon. These groups are hydrolyzed in the presence of water in aqueous solution or air to form glass, minerals, and inorganic fillers. The hydroxyl group on the surface reacts to form reactive silanol. Therefore, silane coupling agents are often used in silicate filled epoxy, phenolic, polyester resin and other systems. In addition, it can also be used in glass fiber reinforced plastic production to improve its mechanical strength and resistance to humid environment. The organic groups of the silane coupling agent are selective to the reaction of synthetic resins. Generally, these organic groups lack sufficient reactivity with synthetic resins such as polyethylene, polypropylene, and polystyrene, so the coupling effect is poor. In recent years, new varieties of silane coupling agents that have a good coupling effect on polyolefins have been developed, but limited to cost and other properties, the application is not widespread. Silane coupling agent is also known as silane treatment agent; primer. The general formula is Y (CH2)nSiX3 in the molecule with more than two different reaction groups of organosilicon monomers, which can be chemically bonded (coupled) with organic and inorganic materials to increase the adhesion of the two materials. In the general formula, n is an integer of 0~3; X is a hydrolyzable group, such as chlorine, methoxy, ethoxy, acetoxy, etc., which is easy to hydrolyze to form silanol, which can react with inorganic substances and combine; Y is an organic functional group, such as vinyl, amino, epoxy, methacryloxy, mercapto, etc., which can react with organic substances and combine. The properties of typical silane coupling agents are shown in the following table: used for surface treatment of glass fibers and inorganic fillers. Used as sealant, adhesive and coating thickener. It is also used to attach immobilized enzymes to the surface of the glass substrate, oil well drilling and sand control, make the masonry surface hydrophobic, make the fluorescent lamp coating have a higher surface resistance, and improve the organic relative glass surface in liquid chromatography Hygroscopicity performance, etc. It is prepared by the addition of silicochloroform and olefins with active groups under the catalysis of platinum catalyst and then alcoholysis. |
| application | 1. mainly used in unsaturated polyester composite materials, it can improve the mechanical properties, electrical properties and light transmission properties of the composite materials, especially the wet properties of the composite materials. 2. The wet mechanical strength and electrical properties of glass fiber reinforced composites can be improved by infiltrating glass fiber (containing the coupling agent). 3. In the wire and cable industry, the EPDM system filled with peroxide crosslinked by clay was treated with the coupling agent, which improved the consumption factor and specific inductance capacitive reactance. 4. Copolymerized with vinyl acetate and acrylic acid or methacrylic acid monomers, these polymers are widely used in coatings, adhesives and sealants, providing excellent adhesion and durability. Silane coupling agent is mainly used in the adhesive industry, which can significantly improve the adhesion of the adhesive, and can be used for adhesives with epoxy, polyurethane, phenolic and other resins. It can also be applied to various inorganic fillers, such as: AL(OH)3, SiO2, glass beads, mica, wollastonite and other inorganic fillers, with obvious effects. It is widely used in glass sealants to improve the adhesion of acrylic latex, sealant, polyurethane and epoxy resin. It is mainly used to improve the bonding performance of organic materials and inorganic materials, such as the treatment of glass fiber in glass fiber reinforced plastic and silicon filler in plastic, rubber, paint, and coating. It is also used in adhesives to increase the bonding performance. The resins it adapts include epoxy, phenolic, melamine, polysulfide polyurethane, polyphenylene, etc. The adhesion of inorganic fillers, substrates and resins is improved, thereby improving the mechanical strength and electrical properties of the composite material, and having a higher retention rate in the wet state. As an inorganic filler surface treatment agent, this product is widely used in clay, glass beads, talcum powder, wollastonite, white carbon black, Shi Ying, aluminum powder and iron powder. This product is suitable for epoxy sealants filled with quartz, epoxy concrete repair materials or coatings filled with sand particles, and epoxy molds filled with metal It can couple the two materials, improve the mechanical strength of the product, and improve the electrical properties of composite materials., Weather resistance and corrosion resistance, suitable for glass fiber reinforced plastic/adhesives, etc. used as surface treatment agent and additive |
Last Update：2024-04-10 22:29:15
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Raw Materials for [3-(2,3-Epoxypropoxy)-propyl]-trimethoxysilane for synthesis